Peroxyacyl nitrate: Difference between revisions

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[[File:Peroxyacetyl-nitrate-3D-balls.png|300px|thumb|Figure 1. Structure of a PAN called peroyacetyl nitrate. Red: oxygen, Blue: nitrogen, Grey: Carbon, White: Hydrogen.<ref>Wikimedia Commons [Online], Available: https://en.wikipedia.org/wiki/Peroxyacetyl_nitrate#/media/File:Peroxyacetyl-nitrate-3D-balls.png</ref>]]
[[File:Peroxyacetyl-nitrate-3D-balls.png|300px|thumb|Figure 1. Structure of a PAN called peroxyacetyl nitrate. Red: [[Oxygen]], Blue: [[Nitrogen]], Grey: [[Carbon]], White: [[Hydrogen]].<ref>Wikimedia Commons [Online], Available: https://en.wikipedia.org/wiki/Peroxyacetyl_nitrate#/media/File:Peroxyacetyl-nitrate-3D-balls.png</ref>]]
<onlyinclude>'''Peroxyacyl nitrates''' or '''PANs''' are a component of [[photochemical smog]], produced in the [[atmosphere]] when oxidized [[volatile organic compound]]s combine with [[nitrogen oxide]].<ref>LaFranchi, B. W.; Wolfe, G. M. (Accessed September 26, 2015). ''Closing the peroxy acetyl nitrate budget: observations of acyl peroxy nitrates (PAN, PPN, and MPAN) during BEARPEX 2007'' [Online], Available: http://www.atmos-chem-phys.net/9/7623/2009/acp-9-7623-2009.html</ref> They are a [[secondary pollutant]] since they form in the atmosphere ''after'' the [[emission]] of [[primary pollutant]]s.</onlyinclude> Sources of the [[pollutant]]s required to create PANs include [[motor vehicle]]s, tobacco smoke, and the burning of [[fossil fuel]]s.
<onlyinclude>'''Peroxyacyl nitrates''' or '''PANs''', which are also referred to as '''acyl peroxy nitrates''' or '''APN''', are a component of [[photochemical smog]], produced in the [[atmosphere]] when [[oxidize|oxidized]] [[volatile organic compound]]s combine with [[nitrogen oxide|nitrogen dioxide]] (<chem>NO2</chem>).<ref>LaFranchi, B. W.; Wolfe, G. M. (Accessed September 26, 2015). ''Closing the peroxy acetyl nitrate budget: observations of acyl peroxy nitrates (PAN, PPN, and MPAN) during BEARPEX 2007'' [Online], Available: http://www.atmos-chem-phys.net/9/7623/2009/acp-9-7623-2009.html</ref> Figure 1 shows the structure of an example of PAN. PANs are a [[secondary pollutant]] since they form in the atmosphere ''after'' the [[emission]] of [[primary pollutant]]s.</onlyinclude> Sources of the [[pollutant]]s required to create PANs include [[motor vehicle]]s, tobacco smoke, and the burning of [[fossil fuel]]s.


==Effects==
==Effects==
PANs have many adverse effects in the human body such as reduced respiratory function and eye irritation, and may also be linked to emphysema, impaired breathing and other lung problems.<ref name=haz>HazMat. (Accessed September 26, 2015). ''Peroxyacetyl Nitrate (PAN)'' [Online], Available: http://www.hazmatmag.com/features/peroxyacetyl-nitrate-pan/</ref> Human exposure to PANs typically occurs in urban centers where automobile and industrial emissions are high.  
PANs have many adverse effects in the human body such as reduced respiratory function (including emphysema and impaired breathing) and eye irritation. <ref name=haz>HazMat. (Accessed September 26, 2015). ''Peroxyacetyl Nitrate (PAN)'' [Online], Available: http://www.hazmatmag.com/features/peroxyacetyl-nitrate-pan/</ref> Human exposure to PANs typically occurs in urban centers where automobile and industrial emissions are high.  


PANs have a lifetime of about 3 months in atmosphere at cold [[temperature]]s of around [[celsius|-20°C]], however in warmer areas it is typically only a few hours. The implications of PANs that remain in the atmosphere for extended periods of time are of concern, since they can be transported large distances thereby spreading their [[environmental impact]] to other regions. Under these conditions PANs can contribute to air [[pollution]] in places far away from their source.<ref>F. Qureshi, University of Colorado Boulder. (Accessed September 26, 2015). ''Peroxyacetyl Nitrates: Ozone in the cooling PAN'' [Online], Available: http://atoc.colorado.edu/~toohey/PAN.pdf</ref>
PANs can remain in the atmosphere for about 3 months after formation, under cold conditions (-20°C and lower). However, in warmer areas, PANs persist only for a few hours. PANs that remain suspended in the atmosphere for extended periods of time are of concern, since they can be transported large distances by wind currents, thereby spreading their impact to other regions. Under these conditions, PANs can contribute to air [[pollution]] in places far away from their source.<ref>F. Qureshi, University of Colorado Boulder. (Accessed September 26, 2015). ''Peroxyacetyl Nitrates: Ozone in the cooling PAN'' [Online], Available: http://atoc.colorado.edu/~toohey/PAN.pdf</ref>


Upon decomposition it can produce a variety of [[chemical]]s like [[carbon monoxide]] and [[carbon dioxide]].<ref name=haz/>
Decomposition of PANs can produce a variety of [[chemical]]s like [[carbon monoxide]] (<chem>CO</chem>) and [[carbon dioxide]] (<chem>CO2</chem>).<ref name=haz/>
 
==For Further Reading==
*[[Photochemical smog]]
*[[Volatile organic compound]]
*[[Secondary pollutant]]
*[[Pollutant]]
*[[Primary pollutant]]
*Or explore a [[Special:Random|random page]]


==References==  
==References==  
{{Reflist}}
{{Reflist}}
[[Category:Ian edit]]
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Revision as of 19:28, 31 January 2020

Figure 1. Structure of a PAN called peroxyacetyl nitrate. Red: Oxygen, Blue: Nitrogen, Grey: Carbon, White: Hydrogen.[1]

Peroxyacyl nitrates or PANs, which are also referred to as acyl peroxy nitrates or APN, are a component of photochemical smog, produced in the atmosphere when oxidized volatile organic compounds combine with nitrogen dioxide ([math]\ce{NO2}[/math]).[2] Figure 1 shows the structure of an example of PAN. PANs are a secondary pollutant since they form in the atmosphere after the emission of primary pollutants. Sources of the pollutants required to create PANs include motor vehicles, tobacco smoke, and the burning of fossil fuels.

Effects

PANs have many adverse effects in the human body such as reduced respiratory function (including emphysema and impaired breathing) and eye irritation. [3] Human exposure to PANs typically occurs in urban centers where automobile and industrial emissions are high.

PANs can remain in the atmosphere for about 3 months after formation, under cold conditions (-20°C and lower). However, in warmer areas, PANs persist only for a few hours. PANs that remain suspended in the atmosphere for extended periods of time are of concern, since they can be transported large distances by wind currents, thereby spreading their impact to other regions. Under these conditions, PANs can contribute to air pollution in places far away from their source.[4]

Decomposition of PANs can produce a variety of chemicals like carbon monoxide ([math]\ce{CO}[/math]) and carbon dioxide ([math]\ce{CO2}[/math]).[3]

For Further Reading

References

  1. Wikimedia Commons [Online], Available: https://en.wikipedia.org/wiki/Peroxyacetyl_nitrate#/media/File:Peroxyacetyl-nitrate-3D-balls.png
  2. LaFranchi, B. W.; Wolfe, G. M. (Accessed September 26, 2015). Closing the peroxy acetyl nitrate budget: observations of acyl peroxy nitrates (PAN, PPN, and MPAN) during BEARPEX 2007 [Online], Available: http://www.atmos-chem-phys.net/9/7623/2009/acp-9-7623-2009.html
  3. 3.0 3.1 HazMat. (Accessed September 26, 2015). Peroxyacetyl Nitrate (PAN) [Online], Available: http://www.hazmatmag.com/features/peroxyacetyl-nitrate-pan/
  4. F. Qureshi, University of Colorado Boulder. (Accessed September 26, 2015). Peroxyacetyl Nitrates: Ozone in the cooling PAN [Online], Available: http://atoc.colorado.edu/~toohey/PAN.pdf