Ground level ozone

Figure 1. Ozone (O3) consists of 3 oxygen atoms bonded together.[1] While essential in the upper atmosphere, near the ground ozone causes breathing problems.

Ground level ozone is a highly reactive secondary pollutant. This pollutant forms when primary pollutants, like hydrocarbons and nitrogen oxides, react with sunlight. Ozone irritates people's lungs and is a major component of photochemical smog.[2] Ground level ozone gives photochemical smog its unpleasant odor and can cause lung function complications, especially in young children.

Formation

Ground level ozone is created by a chemical reaction between volatile organic compounds and nitrogen oxides (Figure 1). The sun and high temperatures act as catalysts to this reaction.[3] This makes its production within warm, densely populated, urban cities a common occurrence. However, since ozone takes some time to form, it will not necessarily stay within these cities. The pollutants may blow down-wind before ozone begins to form, therefore small towns and rural populations may also experience high levels of ozone (Figure 2).[4]

Although emissions of ozone-producing substances have decreased in recent years in Canada (see data visualization below) many urban areas do not yet meet air quality standards.[3]

The pollutants responsible for the formation of ozone are produced by hydrocarbon combustion in vehicles, factories, and power plants. Within cities, vehicles can make up nearly 90% of these pollutants.[3] Nitrogen oxides and VOCs are produced in the morning by cars traveling to work, and ozone is produced shortly after, typically in the afternoon. Since pollutants may flow down-wind from where they are produced, the ozone can find its way around the globe and be produced in safer quantities. However if there is an inversion layer present over the area of production, then the pollutants can be "trapped" over populated cities and form to unsafe levels in the form of smog.[3]

Figure 2. Ozone formation can be seen on the right, in which it is produced from photolyzed nitrogen dioxide.[5]

Health effects

Due to its reactivity and close proximity to the Earth's surface, ground level ozone can have large effects on people. These effects include breathing problems, coughing, and irritation to the eyes, nose, and throat. People with asthma, bronchitis, emphysema, and heart disease may experience aggravated symptoms when exposed to ground level ozone. It can also reduce the body's immune system, increasing the potential for colds and flu. lung function, in particular, may be affected adversely.[2]

Ground level ozone can affect the health of plants and animals. It can also cause damage to rubber, fabrics, and paints. [2]

Visit the EPA to learn more about ground level ozone.

Data Visualization

The line graph below is used to show how levels of various emissions have been improving for Canada as a whole, particularly with efforts to scrub flue gases clean with various air pollution control devices. Ozone is a secondary pollutant, so its emissions cannot be tracked directly. Tracking the primary pollutants that create ozone gives some clue as to what is happening with ozone. NOx and VOCs have been decreasing, which are the two primary pollutants responsible for ozone formation. Please see the page on detailed pollution data for more extensive information on the Canadian release of these pollutants.

For Further Reading

References

  1. "Ozone-CRC-MW-3D-vdW" by Ben Mills - Own work. Licensed under Public Domain via Wikimedia Commons - https://commons.wikimedia.org/wiki/File:Ozone-CRC-MW-3D-vdW.png#/media/File:Ozone-CRC-MW-3D-vdW.png
  2. 2.0 2.1 2.2 G. Tyler Miller, Jr. and D. Hackett, "Table 20-2 Major Outdoor Air Pollutants," in Living in the Environment, 2nd ed. USA: Nelson , 2011, ch.20, sec.2, pp.464
  3. 3.0 3.1 3.2 3.3 R. A. Hinrichs and M. Kleinbach, "Nitrogen oxides, photochemical smog and ozone," in Energy: Its Use and the Environment, 5th ed. Toronto, Ont. Canada: Brooks/Cole, 2013, ch.8, sec.C, pp.250-252
  4. US EPA. (Accessed July 27, 2015). Basic Information [Online], Available: http://www.epa.gov/ozonepollution/basic.html
  5. Adapted from Living In The Environment: G. Tyler Miller, Jr. and D. Hackett, "Photochemical and Industrial Smog," in Living in the Environment, 2nd ed. USA: Nelson , 2011, ch.20, sec.3, pp.465-471.

Authors and Editors

Jordan Hanania, Ashley Sheardown, Kailyn Stenhouse, Jason Donev
Last updated: January 4, 2019
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